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功能侧链液晶聚丙烯酸酯及聚丙烯酰胺的合成
引用本文:黄美荣,李新贵,邵洪涛,伍艳辉.功能侧链液晶聚丙烯酸酯及聚丙烯酰胺的合成[J].功能材料,2002,33(5):465-467.
作者姓名:黄美荣  李新贵  邵洪涛  伍艳辉
作者单位:同济大学,材料学院混凝土材料研究国家重点实验室高分子材料系,上海,200092
基金项目:国家自然科学基金资助项目 (2 980 4 0 0 8和 2 0 1 740 2 8)
摘    要:基于国内外最研究文献,系统论述了两种新型功能性液晶聚合物-侧链液晶聚丙烯酸酯及聚丙酰胺的合成方法,大分子链结构及其液晶相转变温度,指出这类聚合物合成方法简单,一般显示热致性向列型或近晶型液晶相,液晶相转变温度和液晶态温度范围随链结构的不同发生显著变化。

关 键 词:聚丙烯酸酯  聚丙烯酰胺  侧链液晶高分子  合成
文章编号:1001-9731(2002)05-0465-03
修稿时间:2001年9月3日

The synthesis of functional liquid crystalline polyacrylates and polyacrylamide with side chain mesogens
HUANG Mei rong,LI Xin gui,SHAO Hong tao,WU Yan hui.The synthesis of functional liquid crystalline polyacrylates and polyacrylamide with side chain mesogens[J].Journal of Functional Materials,2002,33(5):465-467.
Authors:HUANG Mei rong  LI Xin gui  SHAO Hong tao  WU Yan hui
Abstract:A diseiplinary overview fo the synthesis, the macromolecular chain structure and the liquid crystalline transition temperature for two types of novel functional liquid crystalline polymers- polyacrylates and polyacrylamides with the mesogenic side chain moieties was provided based on the latest literature. It was pointed out that their synthetic methods were simpler, and their liquid crystalline phases were generally thermotropic nemetic or smectic. The liquid crystalline transition temperature and the temperature scope of liquid crystalline phase were altered substantially with the different chain structure.
Keywords:polyacrylate  polyacrylamide  side  chain  liquid  crystalline  polymer  synthesis  
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