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丙烯酸-丙烯酰胺共聚物吸水树脂的制备
引用本文:李廷希,魏萌,赵玉花,袁成前,陈泉良,郝国庆,苏文,李坤. 丙烯酸-丙烯酰胺共聚物吸水树脂的制备[J]. 胶体与聚合物, 2013, 31(2): 67-69
作者姓名:李廷希  魏萌  赵玉花  袁成前  陈泉良  郝国庆  苏文  李坤
作者单位:山东科技大学材料科学与工程学院,山东青岛,266590
摘    要:采用溶液聚合法,以丙烯酸(AA)和丙烯酰胺(AM)为单体,N,N’-亚甲双丙烯酰胺(NMBA)为交联剂,过硫酸铵为引发剂,制备了丙烯酸-丙烯酰胺共聚物吸水树脂,探讨了单体配比(mAA/mAM)、交联剂和引发剂用量对树脂吸水率的影响。结果表明:在65℃时,丙烯酸-丙烯酰胺共聚物吸水树脂的最佳制备条件为:丙烯酸和丙烯酰胺质量比为4:1,交联剂和引发剂用量分别为聚合单体(丙烯酸和丙烯酰胺)总质量的0.02%和0.4%。

关 键 词:丙烯酸  丙烯酰胺  高吸水树脂  吸水性能

Synthesis and Water Absorbency of Poly (Acrylic Acid-co-Acrylamide)
LI Tingxi,WEI Meng,ZHAO Yuhua,YUAN Chengqian,CHEN Quanliang,HAO Guoqing,SU Wen,LI Kun. Synthesis and Water Absorbency of Poly (Acrylic Acid-co-Acrylamide)[J]. Chinese Journal of Colloid and Polymer, 2013, 31(2): 67-69
Authors:LI Tingxi  WEI Meng  ZHAO Yuhua  YUAN Chengqian  CHEN Quanliang  HAO Guoqing  SU Wen  LI Kun
Affiliation:(School of Materials Science and Engineering,Shandong University of Science and Technology,Qingdao 266590)
Abstract:The poly(acrylic acid-co-acrylamide) absorbent resin was prepared by water solution copolymerization using acrylic acid(AA) and acrylamide(AM) as monomers,N,N'-Methylenebisacrylamide(NMBA) as crosslinker and ammonium persulfate(APS) as initiator.The effects of ratio of graft monomers(mAA/mAM),content of crosslinker and initiator on the properties of water absorbency were discussed.The results showed that the optimum reaction conditions were obtained as follows: mAA: mAM= 4: 1,dosage of crosslinker was 0.02% and initiator was 0.4% at 65℃.
Keywords:Acrylic Acid  Acrylamide  Super Absorbent  Water Absorbent Property
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