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Microwave assisted catalytic pyrolysis of bagasse to produce hydrogen
Affiliation:1. School of Resources and Environmental Engineering, East China University of Science and Technology, Shanghai, China;2. National Engineering Research Center for Non-Food Biorefinery, Guangxi Key Laboratory of Biorefinery, Guangxi Academy of Sciences, Nanning, China
Abstract:Using Ni/SiC as a catalyst, bagasse was microwave-assisted pyrolysis in a homemade quartz reactor. The results showed that with the continuous increase of Ni content, the experimental catalytic pyrolysis effect on bio-oil became more and more obvious, and the hydrogen yield gradually increased. When Ni content exceeded 8%, the hydrogen yield and bio-oil catalytic pyrolysis efficiency decreased, and the lowest bio-oil yield was 9.55% when Ni content was 15%, With the increase of power, the catalytic cracking efficiency and hydrogen yield of bio-oil increased, With the increase of catalyst dosage, the catalytic efficiency and the hydrogen yield increase gradually. When the catalyst quality exceeds 1/4 of the material, the growth rate of catalytic efficiency decreases, after alkali treatment, the variation law of hydrogen yield and bio-oil is consistent with that without alkali treatment. In contrast, more hydrogen can be produced after alkali treatment. Under the optimum conditions, the hydrogen yield was 35.85 g/kg biomass.
Keywords:Microwave-assisted  Hydrogen  Bio-oil  Ni/SiC  Alkali treatment
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