Hydrogen sorption behaviour of Mg-5wt.%La alloys after the initial hydrogen absorption process |
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Affiliation: | 1. School of Mechanical and Mining Engineering, The University of Queensland, Brisbane, Queensland, 4072, Australia;2. Australian Synchrotron, ANSTO, Clayton, Victoria, 3168, Australia;3. Department of Applied Quantum Physics and Nuclear Engineering, Kyushu University, Fukuoka, 819-0395, Japan |
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Abstract: | In our earlier study, it has been shown that trace Na additions can improve the reaction kinetics of Mg–5%La (wt.%) alloys during the first absorption. However, the subsequent hydrogen desorption/absorption process of the Mg–5%La after the first absorption has not been investigated. In this study, we have investigated the hydrogen sorption behaviour of the Mg–5%La alloy after the first absorption in terms of phase evolution, and lattice expansion properties during desorption as function of temperature using in-situ synchrotron Powder X-ray Diffraction (PXRD) and in-situ High Voltage Transmission Electron Microscopy (HVTEM). Two distinct phase evolutions, a continuous phase transformation of LaH3 → LaH2 + ½ H2 (from 250 °C) and decomposition of MgH2 → Mg + H2 (between 440 and 460 °C) were identified during the desorption. It is determined that this alloy is cyclable in the absence of Mg12La intermetallic during the subsequent absorption/desorption cycling after the first hydrogen absorption. |
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Keywords: | Mg-based alloys Hydrogen-storage materials Hydrogen absorption/desorption Phase transition Synchrotron diffraction In situ transmission electron microscopy |
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