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Effects of an inhomogeneous electron density distribution on the hydrogen distribution in TiZrTaNbAl multi-principal element alloys
Affiliation:1. School of Physics, University of Electronic Science and Technology of China, Chengdu 610054, China;2. Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, China;3. School of Materials Science and Engineering, The University of New South Wales, Sydney 2052, Australia
Abstract:A body-centered cubic equiatomic TiZrTaNbAl multi-principal element alloy (MPEA) with elemental fluctuations was investigated to further understand the relationship between the microstructure and hydrogen distribution. In this study, a composition dependence of the hydrogen distribution was observed in the TiZrTaNbAl MPEA. An inhomogeneous electron density distribution of the MPEA was revealed by advanced differential phase-contrast scanning electron microscopy (DPC-STEM) for the first time. The results showed that the electron density has a significant effect on the hydrogen distribution in TiZrTaNbAl MPEAs. This work provides new insight into the design of materials with high hydrogen storage capacity and high hydrogen embrittlement resistance.
Keywords:Multi-principal element alloys  Elemental fluctuation  Hydrogen distribution  Electron density distribution
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