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Well-designed NiS/CdS nanoparticles heterojunction for efficient visible-light photocatalytic H2 evolution
Affiliation:1. School of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing, 211167, China;2. Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology, Nanjing, 211167, China;3. College of Environmental Engineering, Nanjing Institute of Technology, Nanjing 211167, China;4. School of Science, China Pharmaceutical University, Nanjing, 211198, China
Abstract:Heterojunction photocatalysts based on semiconducting nanoparticles show excellent performance in many photocatalytic reactions. In this study, 0D/0D heterojunction photocatalysts containing CdS and NiS nanoparticles (NPs) were successfully synthesized by a chemical precipitation method. The NiS NPs were grown in situ on CdS NPs, ensuring intimate contact between the semiconductors and improving the separation efficiency of hole-electron pairs. The obtained NiS/CdS composite delivered a photocatalytic H2 evolution rate (7.49 mmol h?1 g?1), which was 39.42 times as high as that of pure CdS (0.19 mmol h?1 g?1). This study demonstrates the advantages of 0D/0D heterojunction photocatalysts for visible light-driven photocatalytic hydrogen production.
Keywords:NiS/CdS  0D/0D  Intimate contact
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