Hydrogen storage properties of V0.3Ti0.3Cr0.25Mn0.1Nb0.05 high entropy alloy |
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| Affiliation: | 1. School of Mechanical Engineering, Yangzhou University, Yangzhou 225127, PR China;2. Hydrogen Research Institute, Université Du Québec à Trois-Rivières, 3351 des Forges, Trois-Rivières, Québec, G9A 5H7, Canada;3. School of Physical Science and Technology, Yangzhou University, Yangzhou, 225127, PR China |
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| Abstract: | In this paper, we present the synthesis, first hydrogenation kinetics, thermodynamics and effect of cycling on the hydrogen storage properties of a V0.3Ti0.3Cr0.25Mn0.1Nb0.05 high entropy alloy. It was found that the V0.3Ti0.3Cr0.25Mn0.1Nb0.05 alloy crystallizes in body-centred cubic (BCC) phase with a small amount of secondary phase. The first hydrogenation is possible at room temperature without incubation time and reaches a maximum hydrogen storage capacity of 3.45 wt%. The pressure composition isotherm (P–C–I) at 298 K shows a reversible hydrogen desorption capacity of 1.78 wt% and a desorption plateau pressure of 80.2 kPa. The capacity loss is mainly due to the stable hydride with the desorption enthalpy of 31.1 kJ/mol and entropy of 101.8 J/K/mol. The hydrogen absorption capacity decreases with cycling due to incomplete desorption at room temperature. The hydrogen absorption kinetics increases with cycling and the rate-limiting step is diffusion-controlled for hydrogen absorption. |
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| Keywords: | Hydrogen storage material High entropy alloy Hydrogen storage property Cycling stability |
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