Co3Mo3N nanosheets arrays on nickel foam as highly efficient bifunctional electrocatalysts for overall urea electrolysis |
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| Affiliation: | 1. School of Mathematics, Physics and Optoelectronics Engineering, Hubei University of Automotive Technology, Shiyan, 442002, China;2. School of Materials Science and Engineering, Dongguan University of Technology, Dongguan, China;3. Scientific Research Center, Wenzhou Medical University, Wenzhou, 325035, China;4. Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Macau, China;5. Department of Physics and Chemistry, Faculty of Science and Technology, University of Macau, Macau, China |
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| Abstract: | Replacing dynamics-restricted oxygen evolution reaction (OER) with smart urea oxidation reaction (UOR) is very important for reducing the power consumption for hydrogen production. Here, the Co3Mo3N-400/NF is prepared using a facial way, which exhibits remarkable catalytic performances for UOR, hydrogen evolution reaction (HER) and overall urea electrolysis (OUE) because of the more exposed active sites and high electrical conductivity. At 100 mA/cm2, the Co3Mo3N-400/NF shows a small potential of 1.356 V vs. RHE (reversible hydrogen electrode) for UOR, which is much lower than that for OER. Furthermore, for HER, to reach to 100 mA/cm2, a low overpotential of 299 mV is required, and the urea has negligible influence on the HER process. For OUE, the Co3Mo3N-400/NF||Co3Mo3N-400/NF shows a small cell potential of 1.481 V at 100 mA/cm2 along with a good durability. Our work provides more choice for future OUE to generate hydrogen. |
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| Keywords: | UOR OER HER OUE |
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