|
|||||
|
|
Peculiar sandwich-like π–π interaction regulating the nonplanarity of the model heme crystals |
|
| Authors: | Yoshiki Ohgo Akito Hoshino Hidehiro Uekusa Mikio Nakamura |
| Abstract: | X-ray crystallographic analysis of bis(pyridine N-oxide) complexes of iron(III) porphyrinates has revealed that the two pyridine rings of the axial ligands correctly sandwich the porphyrin ring to induce the deformation of commonly observed S4 saddled porphyrin ring. |
| Keywords: | Deformed porphyrin Iron(III), π – π interaction Hemeprotein |
| 本文献已被 ScienceDirect 等数据库收录！ | |