| 聚丙烯/聚苯乙烯/膨润土共混体系的结晶性能和热性能研究 |
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| 引用本文： | 花秀兵,张瑜,阎惠至,陈彦模.聚丙烯/聚苯乙烯/膨润土共混体系的结晶性能和热性能研究[J].合成纤维,2010,39(1):14-16. |
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| 作者姓名： | 花秀兵 张瑜 阎惠至 陈彦模 |
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| 作者单位： | 东华大学材料科学与工程学院纤维材料改性国家重点实验室,上海,201620 |
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| 摘 要： | 通过偏光显微镜(PLM)和光学解偏振仪对聚丙烯/聚苯乙烯/膨润土三元共混体系的结晶形态和等温结晶速率进行了研究。结果表明:共混体系所形成的球晶比纯聚丙烯(PP)所形成的球晶尺寸小,聚苯乙烯(PS)/膨润土(Garamite)复合粒子的加入导致PP的结晶成核和生长发生了改变,加快了PP的结晶速率。同时采用差示扫描量热仪(DSC)对该三元共混体系的热性能进行了研究,结果表明,随着膨润土含量的增加,共混体系熔融温度变高,结晶温度变高,结晶度下降。
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| 关 键 词： | 聚丙烯 聚苯乙烯 膨润土 结晶性能 热性能 |
Research on Crystal and Thermal Properties of the Polypropylene/Polystyrene/Garamite Blend System |
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| HUA Xiu-bing,ZHANG Yu,YAN Hui-zhi,CHEN Yan-mo.Research on Crystal and Thermal Properties of the Polypropylene/Polystyrene/Garamite Blend System[J].Synthetic Fiber in China,2010,39(1):14-16. |
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| Authors: | HUA Xiu-bing ZHANG Yu YAN Hui-zhi CHEN Yan-mo |
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| Affiliation: | (State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China) |
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| Abstract: | The crystalline morphology and crystallization of PP/PS/Garamite blend system was studied through the polarizing microscope （PLM） and optical polarimeter. The results showed that the spherulite formed by blend system was smaller than the spherulite formed by pure PP. The adding of PS/Garamite particles changed the growth of PP and accelerated the crystallization rate of PP. At the same time, the thermal property of the blend system was also studied by using differential scanning calorimeter （DSC）. The results showed that the melting enthalpy and crystallinity were decreased, however, the melting temperature and crystal temperature were increased along with rising of Garamite contents. |
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| Keywords: | polypropylene polystyrene garamite crystal property thermal property |
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