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主客体掺杂型电光聚合物极化条件及弛豫特性研究
引用本文:李琛, 恽斌峰, 胡国华, 崔一平,. 主客体掺杂型电光聚合物极化条件及弛豫特性研究[J]. 电子器件, 2008, 31(6)
作者姓名:李琛   恽斌峰   胡国华   崔一平  
作者单位:东南大学先进光子学中心,南京,210096;东南大学先进光子学中心,南京,210096;东南大学先进光子学中心,南京,210096;东南大学先进光子学中心,南京,210096
基金项目:教育部科学技术研究重点项目  
摘    要:实验利用紫外-可见吸收光谱研究了主客体掺杂型非线性聚合物薄膜(DR1/PMMA)的极化条件与生色团取向有序度、弛豫特性之间的关系.结果表明,在不改变其它条件的情况下,随着极化电压的增加,聚合物薄膜的极化取向有序度、抗弛豫性能得到逐步增强;而在接近于该聚合物薄膜的玻璃化温度情况下进行极化,有助于获得更好的取向有序度和抗弛豫性能.同时实验发现,环境湿度的降低则能显著地增强薄膜偶极子的取向稳定性.

关 键 词:非线性光学  电光聚合物  电晕极化  弛豫

Study on the Poling Conditions and the Relaxation of Guest-Host Electro-Optic Polymer
LI Chen,YUN Bin-feng,HU Guo-hu,CUI Yi-ping. Study on the Poling Conditions and the Relaxation of Guest-Host Electro-Optic Polymer[J]. Journal of Electron Devices, 2008, 31(6)
Authors:LI Chen  YUN Bin-feng  HU Guo-hu  CUI Yi-ping
Affiliation:LI Chen,YUN Bin-feng,HU Guo-hua,CUI Yi-ping(Advanced Photonics Center,Southeast University,Nanjing 210096,China)
Abstract:Taking the guest-host DR1/PMMA films for example,the poling condition on the order parameter and relaxation of the films were studied with UV-Vis spectrum.The results indicate that by poling polymer films with a certain condition,the order parameter and oriented stability improved with the rise of poling voltage and reached the saturation gradually,while the order parameter and oriented stability are better when the poling temperature approaches the glass transition temperature of DR1/PMMA film.Furthermore,...
Keywords:electro-optic polymer  corona poling  relaxation  
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