|
|||||
|
|
Electronic behavior of calcined material obtained by microwave treatment of a tin-O-phenylene-O hybrid copolymer |
|
| Authors: | H. Matsui T. Nishio S. Karuppuchamy M. Yoshihara |
| Affiliation: | a Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1, Kowakae, Higashiosaka, Osaka 577-8502, Japan b Nippon Sheet Glass Co. Ltd., 2-1-7, Kaigan, Minato-ku, Tokyo 105-8552, Japan c Molecular Engineering Institute, Kinki University, 11-6, Kayanomori, Iizuka, Fukuoka 820-8555, Japan |
| Abstract: | Microwave treatment of a mixture of a tin-O-phenylene-O hybrid copolymer and graphite gave SnO2-carbon cluster-Sn composite material. The resulting composite materials were characterized by using XRD, SEM, EDX and TEM. ESR spectral examinations of the calcined materials reveal the possibility of a photo-responsive electron transfer in the process of carbon clusters → SnO2 and/or Sn. The calcined material was found to decompose 7,7,8,8-tetracyanoquinodimethane under light irradiation. |
| Keywords: | Microwave treatment Hybrid copolymer Composite material Carbon clusters SnO2 and electron transfer |
| 本文献已被 ScienceDirect 等数据库收录！ | |