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混合癸烯制备润滑油加氢工艺技术
引用本文:孙淑坤,高宇新,曹婷婷,黄付玲,王爽.混合癸烯制备润滑油加氢工艺技术[J].工业催化,2014,22(5):381-382.
作者姓名:孙淑坤  高宇新  曹婷婷  黄付玲  王爽
作者单位:1.中国石油天然气股份有限公司大庆化工研究中心,黑龙江 大庆 163714; 2.中国石油天然气股份有限公司大庆石化公司热电厂,黑龙江 大庆 163714
摘    要:为了降低加氢后合成油的溴值,以Mo和Ni为加氢催化剂,考察不同反应温度、空速、氢压和氢油体积比对溴值的影响。结果表明,在反应温度320 ℃、空速0.8 h-1、氢压4.0 MPa和氢油体积比550∶1最佳工艺条件下,加氢后合成油的溴值降为0.043 g-Br·(100g油)-1。Mo和Ni加氢催化剂具有优良的烯烃饱和作用。

关 键 词:石油化学工程  混合癸烯  加氢催化剂  润滑油  加氢工艺  

Researches on hydrogenation technology of mixed decene to lubricating oil
SUN Shukun,GAO Yuxin,CAO Tingting,HUANG Fuling,WANG Shuang.Researches on hydrogenation technology of mixed decene to lubricating oil[J].Industrial Catalysis,2014,22(5):381-382.
Authors:SUN Shukun  GAO Yuxin  CAO Tingting  HUANG Fuling  WANG Shuang
Affiliation:1.Daqing Petrochemical Research Center, PetroChina, Daqing 163714, Heilongjiang, China;  2.Thermal Power Plant of Daqing Petrochemical Corporation, PetroChina, Daqing 163714, Heilongjiang, China
Abstract:In order to reduce the bromine values of the hydrogenated synthetic oil,the influence of different temperature,space velocity,hydrogen pressure and volume ratio of hydrogen to oil on the bromine values was investigated using molybdenum and nickel as the catalyst.The results indicated that the bromine value of the hydrogenated synthetic oil reduced to 0.043 g-Br·(100g-oil)-1 under the optimal process condition of reaction temperature 320 ℃,space velocity 0.8 h-1,hydrogen pressure 4.0 MPa,and volume ratio of hydrogen to oil 550∶1.The molybdenum and nickel hydrogenation catalyst has excellent performance of olefin saturation.
Keywords:petrochemical technology  mixed decene  hydrogenation catalyst  lubricating oil  hydrogenation process  
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