| 复合光降解剂对PE薄膜光降解的影响 |
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| 引用本文： | 刘光耀 郑长义. 复合光降解剂对PE薄膜光降解的影响[J]. 现代塑料加工应用, 1997, 9(4): 36-38 |
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| 作者姓名： | 刘光耀 郑长义 |
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| 作者单位： | 中国工程物理研究院应用技术研究发展中心，四川大学化学系，四川大学化学系 成都，610003，成都，610064，成都，610064 |
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| 摘 要： | 通过红外、电子能谱等方法研究了由抗氧剂和光敏剂组成的复合光降解剂对聚乙烯光降解的影响,并对聚乙烯在光降解过程中分子量的变化进行了跟踪测定。研究结果表明,在聚乙烯光降解过程中存在诱导期,其长短主要决定于抗氧剂,而光敏剂则加速诱导期后的光降解。随光降解的进行,聚乙烯薄膜分子量变低并且表面氧化加剧。
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| 关 键 词： | 聚乙烯薄膜 复合光降解剂 诱导期 光降解 |
EFFECT OF MULTIPLE PHOTO DEGRADABLES ON PHOTODEGRADATION OF PE FILM |
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| Liu Guangyao. EFFECT OF MULTIPLE PHOTO DEGRADABLES ON PHOTODEGRADATION OF PE FILM[J]. Modern Plastics Processing and Applications, 1997, 9(4): 36-38 |
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| Authors: | Liu Guangyao |
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| Affiliation: | Liu Guangyao (Research and Development Center of Applied Technology of CAEP)Zheng Changyi Chen Zefang (Chemistry Department of Sichun University) |
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| Abstract: | The effect of multiple photodegradable consisted of antioxidant and photosensitizer on photodegradation of PE film was studied by IR, ESCA etc. , the molecular weights of PE during photodegradation were measured . The results showed that there was an inductive period during photodegradation , which was depended on antioxidant. The photosensitizer could accelerate the photodegradation after the inductive period. With the photodegradation proceeding, the molecular weights decreased and the surfacial oxidation increased. |
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| Keywords: | PE film multiple photodegradable agent inductive period photodegradation |
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