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新一代纤维素基高性能黏合剂的研究和发展
引用本文:邵自强,杨斐霏,王文俊,王飞俊. 新一代纤维素基高性能黏合剂的研究和发展[J]. 火炸药学报, 2006, 29(2): 55-57
作者姓名:邵自强  杨斐霏  王文俊  王飞俊
作者单位:北京理工大学材料科学与工程学院,北京,100081;北京理工大学材料科学与工程学院,北京,100081;北京理工大学材料科学与工程学院,北京,100081;北京理工大学材料科学与工程学院,北京,100081
摘    要:为阐述新一代纤维素基含能黏合剂的研究和发展前景,针对纤维素、硝化纤维素的结构和性能特点,指出由于其大分子链刚性强,使得NC火药普遍存在能量低、制品低温脆、高温软等不足,通过分析近期研究成果和国内外相关资料,综述了纤维素基新型高性能黏合剂研发必要性、化学结构、现状及其应用方向,认为纤维素接枝侧长链增塑后、再在羟基上叠氮化和硝化。作为高性能黏合剂,可极大地提高推进剂的低特征信号、高能和钝感等综合性能。

关 键 词:有机化学  纤维素  含能黏合剂  热塑性  推进剂
文章编号:1007-7812(2006)02-0055-03
收稿时间:2005-03-30
修稿时间:2005-08-20

Research and Development of the New Generation High Performance Cellulose-based Bonder
SHAO Zi-qiang,YANG Fei-fei,WANG Wen-jun,WANG Fei-jun. Research and Development of the New Generation High Performance Cellulose-based Bonder[J]. Chinese Journal of Explosives & Propellants, 2006, 29(2): 55-57
Authors:SHAO Zi-qiang  YANG Fei-fei  WANG Wen-jun  WANG Fei-jun
Affiliation:School of Materials Science and Engineering,Beijing Institute of Technology,Beijing 100081 ,China
Abstract:In order to expatiate on the foreground of the new generation energetic bonder research and development, a shortcoming of low energy, brittleness at low temperature and turning soft at high temperature of the NC powder caused by the rigidity of the NC molecular chain is presented. With the help of the recent research with the internal and overseas status, the necessity of developing the new generation cellulose-based and high performance energetic bonder, the chemical structure, actuality and applied direction of the new energetic bond are summarized. The cellulose plasticized by long carbon chain at the flank, azidonitrified and nitrified at the hydroxyl as a high performance bonder can enhance the synthetical performances of the propellant, e.g. high energy, desenisitivity and low signal.
Keywords:organic chemistry    cellulose    energetic bonder    thermoplastic    propellant
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