Preparation of monodispersed polymer-modified silica particles by radical polymerization using silica colloid and introduction of functional groups on the composite surface |
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| Authors: | Kohji Yoshinaga Takafumi Yokoyama Yutaka Sugawa Hiroyuki Karakawa Naoyuki Enomoto Hiroyasu Nishida Michio Komatsu |
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| Affiliation: | (1) Department of Applied Chemistry, Kyushu Institute of Technology, Sensui, Tobata-ku, 804 Kitakyushu, Japan;(2) Department of Research and Development, Catalysts and Chemicals Industry Company Ltd., Kitaminato, Wakamatsu-ku, 808 Kitakyushu, Japan |
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| Abstract: | Summary Radical polymerizations of vinyl monomers using a initiator of 2,2 -azobis(2-amidinopropane) dihydrochloride on monodispersed silica colloid led to formation of spherical polymer/SiO2 composites, retained particle size. Addition of hydroxypropyl cellulose to the reaction system resulted in yielding excellent dispersible composites into ethanol by short period ultrasonic irradiation. The polymerization of styrene in the presence of mercapto-amine or carboxylic acid derivatives could successfully introduce amino or carboxyl group on the Poly(styrene)/SiO2 composite. |
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