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Microscopic study on the concretion of ceramics in the “Nanhai I” shipwreck of China,Southern Song Dynasty (1,127–1,279 A.D.)
Authors:Xi‐Luo Hao  Tie‐Quan Zhu  Jin‐Jin Xu  Yan‐Rong Wang  Xuan‐Wei Zhang
Affiliation:1. The Key Laboratory of Gas Hydrate, Ministry of Land and Resources, Qingdao Institute of Marine Geology, Qingdao, 266071, China;2. Department of Earth Sciences, Sun Yat‐Sen University, Guangzhou, 510275, China;3. School of Sociology and Anthropology, Sun Yat‐Sen University, Guangzhou, 510275, China;4. Guangdong Mariitme Silk Road Museum, Yangjiang, 529536, China
Abstract:Nanhai I” shipwreck of China Southern Song Dynasty is the oldest and the most integrally preserved shipwreck in the world. The related conservation and archeological research have caught great attention of different experts all over the world. In this study, different types of concretion covered on the surface of the ceramics in “Nanhai I” shipwreck were analyzed by X‐ray diffractometer, micro‐Raman spectrometer, and scanning electron microscope equipped with energy dispersive spectroscopy. Based on the analyses, we found that the grey concretion was mainly composed of quartz, aragonite, and calcite while the reddish concretion was mainly composed of pyrite and quartz. Our study indicated that the formation process of the grey concretion probably included the crystallization and transformation of aragonite, while the corrosion of iron implements and crystallization of pyrite were highly involved in the formation of reddish concretion.
Keywords:aragonite  ceramics  concretion    Nanhai I”  shipwreck
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