AN EXTRACTION STUDY OF LANTHANIDE CHLORO COMPLEXES THE AD0GEN-464C1 - LiCl SYSTEM |
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| Authors: | M. Sohsah J. Krejzler S. Siekierski |
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| Affiliation: | Department of Radiochemistry , Institute of Nuclear Chemistry and Technology , Warsaw, 03-195, Poland |
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| Abstract: | The distribution of lanthanides and yttrium between o-xylene solutions of Adogen-464Cl and aqueous solutions of LiCl was investigated over a broad range of LiCl and extractant concentrations. It has been found that stability constants of inner sphere lantha-nide chloro complexes decrease across the series, whereas the equilibrium constants for the transfer of the negatively charged chloro complexes increase with increasing lanthanide atomic number. |
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