THE EXTRACTION OF RHODIUM FROM AQUEOUS NITRIC ACID BY DINONYLNAPHTHALENE SULPHONIC ACID |
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| Authors: | N. M. Patel J. R. Thornback |
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| Affiliation: | Department of Chemistry Loughborough , University of Technology Loughborough , Leics, LE11 3TU, England |
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| Abstract: | The extraction of rhodium from aqueous nitric acid using dinonylnapthalene sulphonic acid has been investigated. The extraction occurs readily from 0.1M to 1.0m nitric acid and, since the rhodium is extracted as [Rh(H2O)6] 3+into the inverted micelles of the organic solution,equilibration times are less than 5 minutes. Extraction is enhanced by the addition of nitrite ion to form [Rh(H2O)5NO2] 2+as the extracted species. |
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