The reaction of liquid metals to form intermetallics |
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Authors: | G. H. Rodway J. D. Hunt |
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Affiliation: | 1. Department of Metallurgy and Science of Materials, University of Oxford, Parks Road, OX1 3PH, Oxford, UK
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Abstract: | The formation of intermetallic compounds of high melting point, by reaction between liquid metals at low temperatures, was studied for a number of binary systems, in particular Al-Sb, Mg-Sb, Mg-Bi and Na-Bi.Two regimes of behaviour on mixing were found:(1) | Catastrophic exothermic reaction between the liquid metals leading to rapid formation of the compound. | (2) | Non-catastrophic reaction, characterized by the formation of solid intermetallic barrier layers between the reactive liquids. |
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