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离子交换分离磷矿脱镁废水中镁离子的动力学
引用本文:文衍宣,王励生,金作美. 离子交换分离磷矿脱镁废水中镁离子的动力学[J]. 过程工程学报, 2003, 3(6): 523-527
作者姓名:文衍宣  王励生  金作美
作者单位:1. 华南理工大学材料学院,广州,510640;广西大学化学化工学院,南宁530004
2. 四川大学化工学院,成都,610065
摘    要:用动边界模型积分方程描述了001′7树脂脱除磷矿脱镁废水中的Mg2+的有限浴交换动力学,得到了动力学总方程. Mg2+的交换过程属颗粒扩散控制,表观活化能为24.11 kJ/mol,[Mg2+]的表观反应级数为1.0.

关 键 词:磷矿脱镁废水  离子交换  动力学
文章编号:1009-606X(2003)06-0523-06
修稿时间:2003-03-27

Kinetics of Separating Magnesium Ions from Demagging Liquor of Phosphate Ore by Ion Exchange
WEN Yan-xuan,,WANG Li-sheng,JIN Zuo-mei. Kinetics of Separating Magnesium Ions from Demagging Liquor of Phosphate Ore by Ion Exchange[J]. Chinese Journal of Process Engineering, 2003, 3(6): 523-527
Authors:WEN Yan-xuan    WANG Li-sheng  JIN Zuo-mei
Affiliation:WEN Yan-xuan1,2,WANG Li-sheng3,JIN Zuo-mei3
Abstract:An integrating equation of moving boundary model was used to describe the kinetics with changing bulk concentration of removing Mg2+ from demagging waste solution of phosphate ore by 0017 resins. The general kinetical equation was obtained. The ion exchange process of Mg2+ is controlled by ion diffusion through particles. The apparent activation energy is calculated to be 24.11 kJ/mol, and the apparent reaction order of Mg2+ is 1.0.
Keywords:demagging waste solution of phosphate ore  ion exchange  kinetics  
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