Operating characteristics of direct methanol fuel cell using a platinum–ruthenium catalyst supported on porous carbon prepared from mesophase pitch |
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Authors: | Kidon Nam Doohwan Jung Sang-Kyung Kim Donghyun Peck Seungkon Ryu |
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Affiliation: | 1. Advanced Fuel Cell Research Center, Korea Institute of Energy Research, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343, Republic of Korea;2. Department of Chemical Engineering, Chungnam National University, 220 Gung-dong, Yuseong-gu, Daejeon 305-764, Republic of Korea |
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Abstract: | The characteristics of a platinum–ruthenium catalyst supported on porous carbon (PC) are analysed by X-ray diffraction, scanning electron microscopy, cyclic voltammetry and chemisorption techniques. Single-cell tests are carried out in order to compare the performance of these catalysts as an anode in a direct methanol fuel cell with respect to that of a commercial-grade catalyst. The methanol oxidation rate on a Pt–Ru catalyst supported on PC with a pore size of 20 nm is about 35% higher than that on a commercial E-TEK catalyst. The catalyst (Pt–Ru/K20) in the single-cell test gives a power density of 90 and 126 mW cm−2 under air and oxygen at 60 °C, respectively. These values are 15–16% higher than those obtained with a commercial E-TEK catalyst. |
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Keywords: | Direct methanol fuel cell Porous carbon Cyclic voltammetry Single-cell test Platinum&ndash ruthenium catalyst Power density |
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