2-Fatty Acrylic Acids: New Highly Derivatizable Lipophilic Platform Molecules |
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Authors: | Jonathan A. Zerkowski Daniel K. Y. Solaiman |
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Affiliation: | 1. USDA, ARS, Eastern Regional Research Center, 600 E. Mermaid Lane, Wyndmoor, PA, 19038, USA
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Abstract: | This paper reports the incorporation of an alpha-methylene unit into fatty acid skeletons. Since the new olefin is conjugated with the carboxylate, it is susceptible to 1,4-(Michael) additions. We have used multifunctional thiols and amines for additions at the methylene. The resulting products possess clusters of functionality grouped at one end of a hydrophobic tail. These structural patterns will be of use in the design of new types of bio-based surfactants and polymers. One particularly promising pattern of functionality that can be obtained through oxidation and reduction chemistry is a 2-fatty 1,2,3-propanetriol, or a lipophilized glycerol moiety. |
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Keywords: | Oleochemistry Surfactants Detergents Biobased products |
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