煅烧渣土-白云石对水泥砂浆强度和膨胀性能的影响

采用渣土对白云石进行煅烧改性,研究了煅烧渣土-白云石对水泥砂浆强度和膨胀性能的影响规律,并采用X射线衍射仪、扫描电子显微镜和能谱仪研究了掺煅烧渣土-白云石水泥的水化产物性能。结果表明:煅烧渣土-白云石可生成β-C₂S和C₁₂A₇,且随着煅烧温度的提高,β-C₂S和C₁₂A₇的含量增加;煅烧渣土-白云石能够有效促进复合水泥砂浆后期强度的发展,其中掺10%煅烧渣土-白云石水泥砂浆的90 d强度甚至高于纯水泥砂浆;此外,煅烧渣土-白云石中的MgO可水化生成Mg(OH)₂,固相体积增加,促进了水泥砂浆的膨胀,且膨胀率随着煅烧渣土-白云石掺量的增加而增加。研究成果对于提高白云石在水泥混凝土中的应用及减轻建筑垃圾对环境的污染有一定参考价值。

Effects of Calcined Muck-Dolomite on Strengths and Expansion Properties of Cement Mortar

Dolomite was modified through calcination mixed with muck. The effects of calcined muck-dolomite on the strength and expansion properties of cement mortar were investigated. The hydration products of cement containing calcined muck-dolomite were examined by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS). Results show that β-C2S and C12A7 were generated in calcined muck-dolomite, and the content of β-C2S and C12A7 increased with the rising of calcination temperature. The incorporation of calcined muck-dolomite improves the strengths of blended cement mortar effectively at later age. Cement mortar containing 10% calcined muck-dolomite even gain a higher strength at 90 d than pure cement mortars. In addition, the hydration of MgO in calcined muck-dolomite gave rise to Mg(OH)₂, resulting in the expansion of cement mortars, and the expansion rate augmented with the increase of dosage of calcined muck-dolomite. The research finding is of referential value for promoting the application of dolomite in cement concrete and for reducing the pollution of construction wastes.