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Suppressing molecular aggregation in solution processed small molecule organic light emitting diodes
Affiliation:1. Light Technology Institute, Karlsruhe Institute of Technology (KIT), Engesserstrasse 13, 76131 Karlsruhe, Germany;2. Laboratory for Electron Microscopy, Karlsruhe Institute of Technology (KIT), Engesserstrasse 7, 76131 Karlsruhe, Germany;1. Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu 215123, China;2. School of Energy, Soochow University, Suzhou, Jiangsu 215006, China;3. Faculty of Engineering, University of Toyama, Gofuku 3190, Toyama 930-8555, Japan;1. Key Laboratory of Interface Science and Engineering in Advanced Materials of Ministry of Education, Taiyuan University of Technology, Taiyuan, 030024, China;2. Key laboratory of Advanced Display and System Applications, Ministry of Education, Shanghai, 200072, China;3. School of Physical Science and Electronics, Shanxi Datong University, Datong, 037009, China;4. Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan, 030024, China;1. Department of Physics, Durham University, Durham DH1 3LE, United Kingdom;2. Department of Chemistry, Durham University, Durham DH1 3LE, United Kingdom;1. Ames Laboratory-USDOE and Physics & Astronomy Department, Iowa State University, Ames, IA 50011, USA;2. Ames Laboratory-USDOE and Electrical & Computer Engineering Department, Iowa State University, Ames, IA 50011, USA;3. Ames Laboratory-USDOE and Simpson College, Indianola, IA 50125, USA;4. Microelectronics Research Center and Electrical & Computer Engineering Department, Iowa State University, Ames, IA 50011, USA
Abstract:Solution processing of low-molecular weight organic materials for optoelectronic devices is a challenging task due to often strong molecular aggregation. We present a facile and universal route for suppressing the aggregation of molecules during wet-deposition of emission layers for organic light emitting diodes by incorporating electronically inactive polymers. Moderate polymer concentrations of about 10 wt.% lead to only minor changes of the electrical performance while at the same time improving the film formation and consequently the device luminance significantly. The device performance matches the performance of vacuum processed devices with the same device architecture.
Keywords:Organic light emitting diode  Solution processing  Small molecule  Phosphorescent emitter
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