Correlation of microhardness and morphology in injection-moulded poly(ethylene terephtalate)

Microindentation hardness has been applied to a series of injection-moulded poly(ethylene terephtalate) samples prepared using a range of mould temperatures, T _c. The morphology of the samples was characterized by X-ray diffraction and differential scanning calorimetry. Depending on T _c, it is shown that microhardness is lower at the surface than in the core of the mouldings. Results are discussed in terms of the volume fraction of spherulites filling the mouldings which is shown to be dependent upon T _c. The influence of an annealing treatment on the properties of the mouldings is examined. The microhardness values are correlated with the thickness and with the surface free energy of the lamellar crystals. The results obtained indicate that increasing annealing temperatures first leads to an increase and then to a sudden decrease of hardness. The latter can be associated with the changes occurring in the number of defects on the crystal's surface.