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反应性硅氧烷改性VPI环氧树脂的研究
引用本文:郑芸,金晓林,段景宽,江平开. 反应性硅氧烷改性VPI环氧树脂的研究[J]. 绝缘材料, 2008, 41(4)
作者姓名:郑芸  金晓林  段景宽  江平开
作者单位:上海交通大学,化学化工学院,上海,200240;上海市电器绝缘与热老化重点实验室,上海,200240
摘    要:采用反应性硅氧烷作为VPI环氧树脂的活性稀释剂,研究了含有不同反应性基团(环氧基、乙烯基或氨基)的硅氧烷对VPI环氧树脂粘度、储存稳定性、固化反应以及固化物介电性能的影响.结果表明,含有环氧基和乙氧基硅烷结构的硅氧烷对环氧树脂固化反应影响比较小,固化物具有良好的绝缘性能和耐热性.

关 键 词:环氧树脂  硅氧烷  真空压力浸渍(VPI)  活性稀释剂

Modification of VPI Epoxy Resin with Reactive Siloxanes
ZHENG Yun,JIN Xiao-lin,DUAN Jing-kuan,JIANG Ping-kai. Modification of VPI Epoxy Resin with Reactive Siloxanes[J]. Insulating Materials, 2008, 41(4)
Authors:ZHENG Yun  JIN Xiao-lin  DUAN Jing-kuan  JIANG Ping-kai
Abstract:Reactive organosiloxanes were employed as diluents for VPI epoxy resin.The influences of organosiloxanes containing different reactive groups(epoxide,vinyl,or amino) on the epoxy curing reaction and performances of cured epoxy resin were studied and compared.The results show that the diluents containing epoxide and ethoxylsilanes have slight influences on the curing reaction,and the cured epoxy resin exhibites good insulating properties.
Keywords:epoxy resin  siloxane  vacuum pressure impregnation(VPI)  reactive diluent  
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