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Zr_(1-x)T_xMn_(0.6)Ni_(1.4)(T=Ti,V)合金的晶体结构和贮氢特性
引用本文:李玉凤,徐德明,耿鸣明.Zr_(1-x)T_xMn_(0.6)Ni_(1.4)(T=Ti,V)合金的晶体结构和贮氢特性[J].功能材料,1993(1).
作者姓名:李玉凤  徐德明  耿鸣明
作者单位:冶金部钢铁研究总院,冶金部钢铁研究总院,冶金部钢铁研究总院 北京 100081,北京 100081,北京 100081
摘    要:本文研究了Zr_(1-x)T_xMn_(0.6)Ni_(1.4)(T=Ti,V;x=0,0.1,0.2,0.4,0.6)合金的晶体结构和贮氢特性。这种合金的晶体结构属于Laves相的六方结构,空间群为P6_3/mmc。用Ti和V原子替代部分Zr原子后,六方结构的晶格常数变小。六方结构晶格常数的变小致使合金的氢平衡分解压随着Ti和V原子含量的增加而升高。

关 键 词:贮氢合金  P-C-T曲线  Laves相

Crystal Structure and Hydrogen Storage Properties of Zr_(1-x)T_xMn_0.6Ni_1.4(T=Ti, V) Alloys
Li Yu-feng Xu De-ming Geng Ming-ming.Crystal Structure and Hydrogen Storage Properties of Zr_(1-x)T_xMn_0.6Ni_1.4(T=Ti, V) Alloys[J].Journal of Functional Materials,1993(1).
Authors:Li Yu-feng Xu De-ming Geng Ming-ming
Abstract:The crystal structure and hydrogen storage properties of Zr_(1-x)T_xMn_(0.6)Ni_(1.4)(T=Ti, V;x=0, 0.1, 0.2, 0.4,0.6) alloys have been studied. These alloys belong to hexagonal struc ture of Laves phase with space group of P6_3/mmc. After Zr atoms were partically substituted by Ti or V atoms, the crystal constants have decreased and the equilibrium pressure has increased.
Keywords:hydrogen storage alloy  P-C-T curve  Laves phase
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