| 无溶剂合成甲基二羟乙基烯丙基氯化铵 |
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| 引用本文： | 毛桃嫣,郑成,林,陈晓玲,黄晓罗,邢旭,张利萍.无溶剂合成甲基二羟乙基烯丙基氯化铵[J].化工学报,2013,0(5):1884-1889. |
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| 作者姓名： | 毛桃嫣 郑成 林 陈晓玲 黄晓罗 邢旭 张利萍 |
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| 作者单位： | 1. 广西大学化学化工学院, 广西 南宁 530004;
2. 广州大学精细化工研究所, 广东 广州 510006;
3. 广州天赐有机硅科技有限公司, 广东 广州 510660 |
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| 基金项目： | 广东省部产学研项目(20120980);广州市教育局科技项目穗教科[2013]26号;国家级大学生创新训练项目(201211078006)。 |
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| 摘 要： | 引言近十年来,特别是近几年来,有机化学工作者将无溶剂条件下的有机化学反应提出来进行专门的研究。大量研究结果证明1-4],许多有机化学反应可以在无溶剂下进行,取得了令人欣喜的结果。与有溶剂条件下的有机反应相比,无溶剂条件下的有
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| 关 键 词： | 无溶剂合成 甲基二羟乙基烯丙基氯化铵 N-甲基二乙醇胺 |
| 收稿时间： | 2012-08-28 |
| 修稿时间： | 2012-12-25 |
Solvent free synthesis of methyl dihydroxyethyl allyl ammonium chloride |
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| MAO Taoyan,ZHENG Cheng,LIN Jing,CHEN Xiaoling,HUANG Xiaoluo,XING Xu,ZHANG Liping.Solvent free synthesis of methyl dihydroxyethyl allyl ammonium chloride[J].Journal of Chemical Industry and Engineering(China),2013,0(5):1884-1889. |
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| Authors: | MAO Taoyan ZHENG Cheng LIN Jing CHEN Xiaoling HUANG Xiaoluo XING Xu ZHANG Liping |
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| Affiliation: | 1. School of Chemistry & Chemical Engineering, Guangxi University, Nanning 530004, Guangxi, China;
2. Fine Chemicals Research institute, Guangzhou University, Guangzhou 510006, Guangdong, China;
3. Guangzhou Tianci Silicone Technology Co. Ltd., Guangzhou 510660, Guangdong, China |
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| Abstract: | Methyl dihydroxyethyl allyl ammonium chloride(MDAAC)was synthesized from N-methyl diethanolamine( MDEA )and allyl chloride by the solvent-free synthesis method.The effects of reaction time, reaction temperature and reactant molar ratio on reaction conversion rate were studied.The optimum process of synthesizing MDAAC obtained by orthogonal experiment was 60 min reaction time, 50℃ reaction temperature and 1∶1.3 molar ratio of MDEA and allyl chloride.The target product was purified by recrystallization and the yield of product was 97%.The structure of product was characterized by IR,1H NMR and 13C NMR. |
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| Keywords: | solvent-free synthesis methyl dihydroxyethyl allyl ammonium chloride N-methyl diethanolamine" target="_blank">N-methyl diethanolamine')" href="#">N-methyl diethanolamine |
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