异丁烷脱氢裂解制低碳烯烃 |
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引用本文: | 张洁,周明明,李春义,张海涛. 异丁烷脱氢裂解制低碳烯烃[J]. 石油炼制与化工, 2013, 44(5): 14-18 |
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作者姓名: | 张洁 周明明 李春义 张海涛 |
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作者单位: | 1. 中国石油大学(华东)化学工程学院重质油国家重点实验室 2. 中国石油石油化工研究院兰州化工研究中心 |
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基金项目: | 国家重点基础研究发展计划(973)项目 |
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摘 要: | 以异丁烷为原料,在固定床微反实验装置上考察了其在Cr2O3/Al2O3脱氢催化剂和HZSM-5催化剂组成的混合催化剂上脱氢裂解反应的情况。研究发现:两种催化剂在反应器中的分布状态以及Cr2O3/Al2O3催化剂的装填量都会对反应结果产生很大的影响,当两者均匀混合、Cr2O3/Al2O3催化剂的添加量为20%时,裂解反应效果最佳,转化率达到80.99%,三烯总收率为50.26%,其中乙烯、丙烯和丁烯的收率分别为12.42%,24.41%,13.43%;相比于单纯的HZSM-5催化剂,转化率提高了21.22百分点,三烯的选择性提高了2.57百分点。此外,反应过程中采用异丁烷和惰性稀释气(N2)混合进料时,反应效果更佳,而且随稀释比增大,优势更明显。
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收稿时间: | 2012-09-03 |
修稿时间: | 2012-10-24 |
DEHYDROGENATION CRACKING OF i-BUTANE TO PRODUCE LIGHT OLEFINS |
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Abstract: | The dehydrogenation cracking of i-butane was studied over mixed catalysts comprised of Cr2O3/Al2O3 dehydrogenation catalyst and HZSM-5 catalyst in a fixed-bed reactor. The results demonstrate that conversion and product distribution vary signi?cantly depending on different location of Cr2O3/Al2O3 and HZSM-5 catalyst and the amount of Cr2O3/Al2O3 catalyst in the reactor, and the reaction performance is the best when two kinds of catalysts are homogeneously mixed. On the mixed catalyst HZSM-5 with a 20% Cr2O3/Al2O3, the conversion of reaction is 81%, and the yield of ethylene, propylene and butylene is 12.4%, 24.1% and 13.4%, respectively. The conversion increases by 21% and the selectivity of total olefins (ethylene, propylene and butylene) increases by 2.57%, compared with the pure HZSM-5. Besides, i-butane mixed with N2 enters the reactor at a fixed residence time of i-butane, the reaction results become better, and the advantage are more obvious as dilution ratio increases. |
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