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Discontinuities in the porous anodic film formed on AA2099-T8 aluminium alloy
Authors:Y. Ma  X. Zhou  G.E. Thompson  M. Curioni  X. Zhong  E. Koroleva  P. Skeldon  P. Thomson  M. Fowles
Affiliation:aCorrosion and Protection Centre, School of Materials, The University of Manchester, Manchester M13 9PL, UK;bAirbus Operations Limited, Chester Road, Broughton, Chester CH4 0DR, UK
Abstract:The anodizing behaviour of constituent particles (Al–Fe–Mn–Cu) and dispersoids (Al–Cu–Mn–Li and β′(Al3Zr)) in AA2099-T8 has been investigated. Low-copper-containing Al–Fe–Mn–Cu particles anodized more slowly than the alloy matrix, forming a highly porous anodic oxide film. Medium- and high-copper-containing Al–Fe–Mn–Cu particles were rapidly dissolved, resulting in defects in the anodic film. The anodizing of Al–Cu–Mn–Li dispersoids is slightly slower than the alloy matrix, forming a less regular anodic oxide film. β′(Al3Zr) dispersoids anodized at a similar rate to the alloy matrix. Further, the potential impact of the discontinuities in the resultant anodic films on the performance of the filmed alloy is discussed.
Keywords:A. Aluminium   A. Lithium   A. Intermetallics   C. Anodic films   C. Oxidation
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