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紫外光下Ag掺杂TiO2薄膜基底对VO2相转变温度的影响
引用本文:郑金玉,吴梁鹏,王学伟,周凤玲,徐刚,李新军. 紫外光下Ag掺杂TiO2薄膜基底对VO2相转变温度的影响[J]. 新能源进展, 2014, 2(1): 59-62. DOI: 10.3969/j.issn.2095-560X.2014.01.010
作者姓名:郑金玉  吴梁鹏  王学伟  周凤玲  徐刚  李新军
作者单位:1. 中国科学院广州能源研究所,中国科学院可再生能源重点实验室,广州 510640;2. 深圳市环境工程科学技术中心有限公司,深圳 518057;3. 莫纳什大学克雷顿校区化学系,维多利亚,澳大利亚 3800
基金项目:广州市科技计划项目(2013J4300035);国家自然科学基金项目(51172233);广东省水与大气污染防治重点实验室基金项目(GD2012A05)
摘    要:利用溶胶−凝胶法和浸渍提拉技术制备了不同结构银掺杂二氧化钛薄膜为基底材料的VO2薄膜,考察了Ag分级配置的二氧化钛薄膜基底材料对VO2薄膜相变温度的影响。在紫外灯照射下测试面内电阻随温度,电压随时间的变化,结果表明基底材料为Ag分级配置的VO2/TiO2薄膜相变温度点明显降低。这可能是由于光照条件下空穴载流子从基底材料注入到VO2薄膜导致相变温度点偏移。因此,不同结构银掺杂二氧化钛薄膜为基底材料的VO2薄膜能够根据环境温度和太阳光线变化而应用于光热致变色智能窗。

关 键 词:银掺杂二氧化钛  VO2  相转变温度  
收稿时间:2013-12-20

Effect of Ag Doping TiO2 on the Phase Transition Temperature Point of VO2 under Ultraviolet Light Irradiation
ZHENG Jin-yu,WU Liang-peng,WANG Xue-wei,ZHOU Feng-ling,XU Gang,LI Xin-jun. Effect of Ag Doping TiO2 on the Phase Transition Temperature Point of VO2 under Ultraviolet Light Irradiation[J]. Advances in New and Renewable Energy, 2014, 2(1): 59-62. DOI: 10.3969/j.issn.2095-560X.2014.01.010
Authors:ZHENG Jin-yu  WU Liang-peng  WANG Xue-wei  ZHOU Feng-ling  XU Gang  LI Xin-jun
Affiliation:1. Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
2. Shenzhen Environmental Engineering Science & Technology Center Co. Ltd., Shenzhen 518057, China;
3. School of Chemistry, Monash University Clayton, Victoria 3800, Australia
Abstract:The transition metal oxide (TMO) film, VO2, was fabricated on Ag doping titanium oxide substrates by sol-gel method. By the measurement of in-plane resistance varied with temperature under ultraviolet light irradiation, an obvious decrease in the phase transition temperature point was observed for VO2/TiO2 with a silver hierarchical configuration. The reason why the phase transition temperature point shift was discussed base on the voltage measurement under light irradiation that indicated hole-carrier injection from the substrate to the VO2 film. The TMO film could be applied as a photo-thermochromic smart window to enable automatic solar/heat control in response to environmental temperature and solar light.
Keywords:Ag doping titanium oxide  VO2  phase transition temperature point  
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