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Comparison of the performance of masterbatch and liquid color concentrates for mass coloration of polypropylene
Authors:Sonja Haastrup  Donghong Yu  Thomas Broch  Kim Lambertsen Larsen
Affiliation:1. Department of Chemistry and Bioscience, Aalborg University, Aalborg East, Denmark;2. Fibertex Personal Care? a/S, Aalborg East, Denmark
Abstract:The properties of polypropylene (PP) mixed with masterbatch (MB) and liquid color concentrates (LCC), respectively, were compared by preparing samples of PP with MB and PP with LCC and neat PP as a reference material using 1–4 extrusion cycles. Two colors were examined, i.e., a white color consisting of pigment white 6, and a green color consisting of pigment white 6, pigment blue 15:3, and pigment green 7. The color difference between PP prepared with MB and LCC was determined and the mechanical, rheological, and crystalline properties of PP prepared with MB and LCC were found to be generic. The color of PP obtained from MB and LCC were comparable. Further, it was found that the tensile strength, the viscosity, and the crystal structure obtained were similar when using LCC instead of MB. The viscosity of the treated PP generally decreased with increasing extruder retention time due to thermal degradation. The tensile strength and the crystal structure were independent of increased extruder retention time. © 2015 Wiley Periodicals, Inc. Col Res Appl, 41, 484–492, 2016
Keywords:colorimetry  masterbatch  liquid color concentrate  polypropylene  CIE system  crystallization  tensile testing  polymer rheology
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