Glass transition of poly(oxymethylene)

Heat capacity data of semicrystalline poly(oxymethylene) samples. Delrin and Celcon, are analysed in order to discuss the glass transition behaviour of this polymer. There are two types of non-crystalline poly(oxymetheylene). the mobile and rigid amorphous parts. The glass transition of the former occurs in a rather wider range of temperature: it starts at 180 K and could end at 265 K. The latter, under restraint due to the crystallites, remains frozen up to the melting temperature.