| 二氢月桂烯高效合成香茅醇 |
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| 引用本文： | 冉学光,江焕峰,朱新海,许琳. 二氢月桂烯高效合成香茅醇[J]. 精细化工, 2003, 20(12): 746-748,751 |
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| 作者姓名： | 冉学光 江焕峰 朱新海 许琳 |
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| 作者单位： | 中国科学院,广州化学研究所,广东,广州,510650 |
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| 基金项目： | 国家自然科学基金资助项目(No.20172053)~~ |
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| 摘 要： | 用一种硼氢化试剂———丙二酸与硼氢化钠反应生成的丙二酰氧基硼氢化钠在THF中与二氢月桂烯反应制备香茅醇。温度60℃,反应时间为6h时,反应100%发生在末端双键上,氧化生成香茅醇的质量分数大于90%,该条件下没有发现酮生成。
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| 关 键 词： | 二氢月桂烯 硼氢化 香茅醇 |
| 文章编号： | 1003-5214(2003)12-0746-04 |
A Good Method for Preparation of Citronellol with Dihydromyrcene |
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| RAN Xue-guang,JIANG Huan-feng,ZHU Xin-hai,XU Lin. A Good Method for Preparation of Citronellol with Dihydromyrcene[J]. Fine Chemicals, 2003, 20(12): 746-748,751 |
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| Authors: | RAN Xue-guang JIANG Huan-feng ZHU Xin-hai XU Lin |
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| Abstract: | Malonyloxyborohydride,a hydroboration reagent,is prepared by reaction of malonic acid and sodium borohydride,and is used to react with dihydromyrcene in THF.At 60 ℃,90% of boron atoms added to the terminal position on the terminal double bond after 6 h.Oxidation of the addition product gives citronellol with purity >90%.Ketone is not found.The internal double bond of dihydromyrcene is not involved in this reaction. |
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| Keywords: | dihydromyrcene hydroboration citronellol |
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