延缓交联弱凝胶调驱剂的研制与性能评价 |
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引用本文: | 刘平德,张松,冯爱丽,秦杰.延缓交联弱凝胶调驱剂的研制与性能评价[J].石油钻采工艺,2013,35(3):90-93. |
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作者姓名: | 刘平德 张松 冯爱丽 秦杰 |
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作者单位: | 1.中国石油勘探开发研究院,北京 100083 |
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摘 要: | 现有交联聚合物凝胶体系成胶时间短,调驱剂不能深入油藏实现深部放置,导致了水驱开发效果较差。考察了在一定温度、热稳定剂作用下,延缓有机复合交联剂NQJ与聚合物的交联反应,形成了适用于大庆萨尔图北部油田油藏的延缓交联弱凝胶体系。该体系地面黏度较低,便于现场注入,且具有较好的延缓交联效果,可实现大剂量深部调驱。研究结果表明:抗盐聚合物、交联剂与热稳定剂的质量分数分别为0.15%~0.25%、0.15%~0.2%与0.015%~0.025%时,形成的凝胶黏度大于5 000 mPa·s,成胶时间3~6 d可调,能够满足现场深部调驱要求。
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关 键 词: | 调驱 弱凝胶 延缓交联 热稳定性 提高采收率 |
收稿时间: | 2019-05-18 |
Research of a retarding crosslink weak gel for conformance control and displacement and its performance evaluation |
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Affiliation: | 1.Research Institute of Petroleum Exploration &2.Development, PetroChina, Beijing 100083, China3.Key Laboratory of Oil & |
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Abstract: | Due to the short gelation time of the present cross-linked polymer gel system, conformance control agent cannot enter into deep reservoir, resulting in poor water flooding effect. By the crosslinking reaction between the retarding organic composite cross-linking agent NQJ and salt-resistance polymer under thermal stabilizers and specific temperature, the weak gel with space network structure is formed. The weak gel conformance control agent has low surface viscosity, easy injection on-site, and good delayed cross-linking effect, so it can achieve the high-dose injection. The research shows that the mass fraction of salt-resistance polymer, cross-linking agent, and the heat stabilizer are 0.15%-0.25%, 0.15%-0.2%, and 0.015%-0.025% respectively. The viscosity of gel is greater than 5000 mPa·s, and the gelation time is 3~6 days. The weak gel can meet the need of deep reservoir conformance control and oil displacement, and improve the water flooding effect of high water cut oil field. |
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