A 3-D silver(I) polymer with 5,6-dihydro-1,4-dithiin-2,3-dicarboxylate ligand,showing an unusual 6-connected (412.63)2(49.66) topology |
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| Authors: | Min Hu Qiang Zhang Li-Ming Zhou Shao-Ming Fang Chun-Sen Liu |
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| Affiliation: | Zhengzhou University of Light Industry, Henan Provincial Key Lab of Surface & Interface Science, Zhengzhou, Henan 450002, China |
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| Abstract: | The in situ reaction of AgClO4·6H2O with 5,6-dihydro-1,4-dithiin-2,3-dicarboxylic anhydride in the presence of lithium hydroxide afforded a photoluminescent three-dimensional (3-D) AgI coordination polymer, Ag2(L)]∞ (1), which exhibited an unusual trinodal 6-connected (412.63)2(49.66) topological net (L = 5,6-dihydro-1,4-dithiin-2,3-dicarboxylate). Moreover, the luminescent/thermal properties of 1 have also been briefly investigated. |
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