Metal-controlled assembly of coordination polymers: Structural variation from 2D parallel interpenetration to 3D CsCl-type topology |
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Authors: | Jin Yang Guang-Bo Che Bo Liu Ying-Ying Liu Jian-Fang Ma |
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Affiliation: | 1. Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, People’s Republic of China;2. College of Chemistry, Jilin Normal University, Siping 136000, People’s Republic of China |
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Abstract: | Two novel metal-organic frameworks [Cd2(hdb)2(1,4-ndc)2]n (1) and [Ni3(Hhdb)2(1,4-ndc)4(H2O)2]n (2) have been synthesized under the similar hydrothermal conditions (hdb = 1,1′-(1,6-hexanediyl)bis(imidazole) and 1,4-ndc = 1,4-naphthalenedicarboxylate). The polymers (1) and (2) show 2D parallel interpenetration and 3D CsCl-type topology, respectively, which are mainly affected by the differences of the metal centers. |
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