Hydrothermal synthesis,crystal structure and electrochemical property of a novel 3-D microporous reduced molybdophosphate with large cavities |
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| Authors: | Hong-Xu Guo Xi-Zhong Li Wen Weng |
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| Affiliation: | Department of Chemistry & Environmental Science, Zhangzhou Normal University, Zhangzhou 363000, PR China |
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| Abstract: | A novel molybdenum phosphate based on [Mo6P4] inorganic subunits and [Mn(H2O)2]2+ cations, Mn[Mo6O12(OH)3(PO4)(HPO4)2(H2PO4)]2[Mn(H2O)2]2(Hen)4·13H2O (en = ethyl enediamine), has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, EPR spectrum and TGA analysis. The 3-D framework of the compound contains microporous structure with large cavities filled by mono-protonated Hen+ and water molecules. The electrochemical behavior of the compound has been also studied. |
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