Abstract: | Thermal decomposition of titanium(IV) tetra-tert-butoxide (TTB) in inert organic solvents at 573 K yielded microcrystalline
anatase (titanium(IV) oxide, TiO2) powders with a crystallite size of ca. 9 nm and a surface area of <100 m2 g-1. Primary and secondary alkoxides of titanium(IV), however, were not decomposed under similar conditions, indicating that
the thermal stability of C-O bonds in the alkoxides was a decisive factor for their decomposition. The TiO2 prepared from TTB by this manner was thermally stable upon calcination in air and retained high surface area of ca. 100 m2 g-1 even after calcination at 823 K. The as-prepared TiO2 powders, without calcination, exhibited much higher rate of carbon dioxide formation than any other active photocatalysts
such as Degussa P-25 and Ishihara ST-01 in the photocatalytic mineralization of acetic acid in aerated aqueous solutions.
The higher activity of the present TiO2 photocatalysts is attributed to both high crystallinity and large surface of the present product. The calcination of the
as-prepared TiO2 in air reduced the photocatalytic activity, but it was still higher than the other commercially available TiO2's.
This revised version was published online in July 2006 with corrections to the Cover Date. |