Pressure dependence of limiting current density of sparking during electrochemical drilling |
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Authors: | B Sajdl I Rou?ar |
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Affiliation: | (1) J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, 182 23 Prague 8, Czech Republic;(2) Department of Inorganic Technology, University of Chemical Technology, 166 28 Prague 6, Czech Republic |
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Abstract: | The cathodic current density used in electrochemical drilling can be increased only up to a certain value, above which current oscillations, sparking and acoustic phenomena appear, whereby the cathode can be damaged. The limiting current density for sparking, j
s, depends on the rate of flow and properties of the electrolyte and on the hydrostatic pressure. Values of j
s were measured for metal capillaries provided with external insulation in the turbulent flow regime in the range of Reynolds numbers from 2 300 up to 30 000 and at hydrostatic pressures ranging from 0.12 to 1.1 MPa. A simple heat generation model is proposed and the limiting current densities for sparking (868 experiments) are correlated with a criterion equation enabling the calculation of j
s.List of symbols
c
pE
specific heat of electrolyte (J kg–1 K–1)
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d
1
inner diameter of the cathode (m)
-
d
2
outer diameter of the cathode (m)
-
I
current (A)
-
I
s
limiting current for sparking (A)
-
j
current density (Am–2)
-
j
s
limiting current density for sparking (Am–2) KT constant
-
K
T
constant
-
L
characteristic length (m)
-
N
u
Nusselt number
-
p
pressure (Pa)
-
p
0
reference atmospheric pressure (Pa)
-
P
exponent
-
P
r
Prandtl number
-
q
exponent
-
q
heat flux (W m–2)
-
R
exponent
-
Re
Reynolds number
- E
linear electrolyte velocity (m s–1) Greek symbols
-
heat transfer coefficient (W m–2 K–1)
-
temperature difference (K)
- E
electrolyte conductivity ( –1 m–1)
- E
electrolyte thermal conductivity (Wm–1 K–1)
- µE
electrolyte viscosity (kgm–1 s–1)
- E
electrolyte density (kg m–3) |
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Keywords: | |
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