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Pressure dependence of limiting current density of sparking during electrochemical drilling
Authors:B Sajdl  I Rou?ar
Affiliation:(1) J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, 182 23 Prague 8, Czech Republic;(2) Department of Inorganic Technology, University of Chemical Technology, 166 28 Prague 6, Czech Republic
Abstract:The cathodic current density used in electrochemical drilling can be increased only up to a certain value, above which current oscillations, sparking and acoustic phenomena appear, whereby the cathode can be damaged. The limiting current density for sparking, j s, depends on the rate of flow and properties of the electrolyte and on the hydrostatic pressure. Values of j s were measured for metal capillaries provided with external insulation in the turbulent flow regime in the range of Reynolds numbers from 2 300 up to 30 000 and at hydrostatic pressures ranging from 0.12 to 1.1 MPa. A simple heat generation model is proposed and the limiting current densities for sparking (868 experiments) are correlated with a criterion equation enabling the calculation of j s.List of symbols c pE specific heat of electrolyte (J kg–1 K–1) - d 1 inner diameter of the cathode (m) - d 2 outer diameter of the cathode (m) - I current (A) - I s limiting current for sparking (A) - j current density (Am–2) - j s limiting current density for sparking (Am–2) KT constant - K T constant - L characteristic length (m) - N u Nusselt number - p pressure (Pa) - p 0 reference atmospheric pressure (Pa) - P exponent - P r Prandtl number - q exponent - q heat flux (W m–2) - R exponent - Re Reynolds number - ngrE linear electrolyte velocity (m s–1) Greek symbols - agr heat transfer coefficient (W m–2 K–1) - chi temperature difference (K) - kappaE electrolyte conductivity (OHgr–1 m–1) - lambdaE electrolyte thermal conductivity (Wm–1 K–1) - µE electrolyte viscosity (kgm–1 s–1) - rhovE electrolyte density (kg m–3)
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