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Effect of deashing rice straws on their derived activated carbons produced by phosphoric acid activation
Authors:AH Basta  V FierroH Saied  A Celzard
Affiliation:a National Research Centre, Cellulose & Paper Dept., El-Tahrir Street, Dokki 12622, Cairo, Egypt
b Institut Jean Lamour - UMR CNRS 7198, CNRS - Nancy-Université - UPV-Metz, Département Chimie et Physique des Solides et des Surfaces. ENSTIB, 27 ruePhilippe Séguin, BP 1041, 88051 Épinal cedex 9, France
Abstract:We studied the effect of physically and/or chemically deashing rice straw (RS) on the adsorption capacity of their derived activated carbons (ACs) produced by chemical activation with H3PO4. Surface area and pore volumes were determined by nitrogen adsorption at 77 K. Methylene blue adsorption isotherms onto ACs were carried out, and we applied Langmuir and Freundlich models to fit the adsorption data. We showed that preliminary deashing does not bring significant improvement to the resultant ACs’ properties. ACs prepared by H3PO4 activation of raw and deashed RS have intermediate performances between those of ACs prepared by 1- and 2-step KOH activation, but are much cheaper to produce.
Keywords:Activated carbon  Rice straw  Chemical activation  Phosphoric acid  Adsorption
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