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非离子型腈纶油剂的研制
引用本文:何玉莲,崔永福,赵锡武.非离子型腈纶油剂的研制[J].合成纤维工业,2008,31(3).
作者姓名:何玉莲  崔永福  赵锡武
作者单位:1. 中国石油大庆化工研究中心,大庆,163714
2. 大庆石化公司电子商务部,大庆,163714
摘    要:以4-仲丁基-2,6-二叔丁基苯酚、环氧乙烷为原料,KOH为催化剂,合成4-仲丁基-2,6-二叔丁基苯酚聚氧乙烯醚抗静电剂,与山梨醇单硬脂肪酸酯、蓖麻油聚氧乙烯醚、十二胺醚等表面活性剂复配成非离子型腈纶油剂。结果表明:上油后的腈纶短纤维的质量比电阻为2.1×10~8Ω·g/cm~2,摩擦系数适中,能满足腈纶生产和加工要求。

关 键 词:聚丙烯腈纤维  非离子表面活性剂  多烷基苯酚聚氧乙烯醚  抗静电性能

Development of non-ionic finishes for PAN fiber
He Yulian,Cui Yongfu,Zhao Xiwu.Development of non-ionic finishes for PAN fiber[J].China Synthetic Fiber Industry,2008,31(3).
Authors:He Yulian  Cui Yongfu  Zhao Xiwu
Abstract:An antistatic agent of 4-sec-butyl-2,6-di-tert-butylphenol polyoxyethylene ether was synthesized from 4-sec-butyl-2, 6-di-tert-butylpbenol and ethylene oxide with KOH as a catalyst,from which a non-ionic finish was prepared by the complex for- mulation with the surfactants of sorbitan monostearate,polyoxyethylene ether castor oil and dodecylamine ether.The results showed that the PAN staple fiber had the mass specific resistance 2.1×10~8Ω·g/cm~2 and moderate friction coefficient,satisfy- ing the production and processing requirements of PAN fiber.
Keywords:polyacrylonitrile fiber  non-ionic surfactant  alkyl-phenol polyoxyethylene ether  antistatic property
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