| 新型巯基棉分离富集-ICP-AES法测定含铜物料中的金、银 |
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| 引用本文： | 陈永欣,黎香荣,杨俊,谢毓群,罗明贵. 新型巯基棉分离富集-ICP-AES法测定含铜物料中的金、银[J]. 黄金, 2009, 30(2): 49-52 |
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| 作者姓名： | 陈永欣 黎香荣 杨俊 谢毓群 罗明贵 |
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| 作者单位： | 防城港出入境检验检疫局;中国检验认证集团广西有限公司 |
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| 摘 要： | 合铜物料（铜矿石、铜精矿、铜锍等）经混合酸溶解后，在10％HCl介质中，采用新型巯基棉分离富集-电感耦合等离子体原子发射光谱法测定Au，Ag。对巯基棉制备方法、溶样条件、分离富集条件、共存元素及基体干扰等进行了实验，结果表明，含铜物料中常见的12种共存元素对该方法测定金、银不产生干扰，方法基体效应较小，各待测元素之间也没有明显干扰。在最佳仪器工作条件下，方法的回收率为97．0％～103．0％，相对标准偏差RSD（n=12）为0．75％-1．95％。采用该方法分析测定标准物质和不同产地的实际样品，分析结果与推荐值和其他常规方法测定值一致，均在允许误差范围内。该方法与现行的单元素分析测定方法相比，简便快速，结果可靠，适用于大批量含铜物料进出口检验。
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| 关 键 词： | 巯基棉 金 银 含铜物料 电感耦合等离子体原子发射光谱法 |
Determination of gold and silver in copper-containing materials with separating and enriching of new SCF by Inductively Coupled Plasma-Atomic Emission Spectrometric |
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| Chen Yongxin,Li Xiangrong,Yang Jun,Xie Yuqun,Luo Minggui. Determination of gold and silver in copper-containing materials with separating and enriching of new SCF by Inductively Coupled Plasma-Atomic Emission Spectrometric[J]. Gold, 2009, 30(2): 49-52 |
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| Authors: | Chen Yongxin Li Xiangrong Yang Jun Xie Yuqun Luo Minggui |
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| Affiliation: | 1.Fangchenggang Entry-Exit Inspection and Quarantine Bureau;2.Guangxi Co.;LTD.;China Certification & Inspection Group |
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| Abstract: | First,copper-containing materials(copper ore,copper concentrate,copper matte etc.) are dissolved with mixed acids.And then,gold and silver are separated and enriched by sulfhydryl cotton fiber(SCF) in 10% HCl solution.Then gold and silver are determined with inductively coupled plasma-atomic emission spectrometric.The preparation of SCF,the sample slaking conditions,the separating and enriching conditions and the interference between matrix and concurrent elements are discussed.Twelve concurrent elements ha... |
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| Keywords: | sulfhydryl cotton fiber （SCF） element determination gold silver copper-containing materials induetively coupled plasma-atomic emission spectrometry |
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