Dark current and photovoltage models on the formation of depletion region in C60/NPB organic heterojunctions |
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Authors: | Qiujian Sun Guifang DongLian Duan Liduo WangYong Qiu |
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Affiliation: | Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, PR China |
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Abstract: | We establish quantitative models on the formation of depletion regions in organic photodiodes (OPD) based on fullerene/N,N′-diphenyl-N,N′-bis(1-naphthyl)-1,1′-biphenyl-4,4′-diamine (C60/NPB) heterojunctions. The models describe the relation of dark current and open-circuit voltage to the deposited thickness of C60 or NPB. Interfacial electronic structures, such as built-in potential, the charge density, the minimized thicknesses of completely developed depletion regions and the energy level bending on each side of the heterojunction were derived from the fitting model. Also, we observed a shift of depletion region from NPB to C60 due to the relative change of charge density under illumination. The device performance proved the reasonability of the models. This paper provides a universally applicable method to probe the interfacial information of organic semiconductors. |
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Keywords: | Organic heterojunction Organic photodiode Depletion region Interfacial electronic structure Fitting model |
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