Synthesis gas production using oxygen storage materials as oxygen carrier over circulating fluidized bed |
| |
Authors: | Xiaoping DAI Changchun YU Ranjia LI Qiong WU Zhengping HAO |
| |
Affiliation: | aThe Key Laboratory of Catalysis CNPC, University of Petroleum, Beijing 102249, China;bResearch Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China |
| |
Abstract: | A novel process for synthesis gas production over Circulating Fluidized Bed (CFB) using oxygen storage materials as oxygen carrier was reported. First, oxygen in the air was chemically fixed and converted to lattice oxygen of oxygen storage materials over regenerator, and then methane was selectively oxidized to synthesis gas with lattice oxygen of oxygen storage materials over riser reactor. The results from simulation reaction of CFB by sequential redox reaction on a fixed bed reactor using lanthanum-based perovskite LaFeO3 and La0.8Sr0.2Fe0.9Co0.1O3 oxides prepared by sol-gel, suggested that the depleted oxygen species could be regenerated, and methane could be oxidized to synthesis gas by lattice oxygen with high selectivity. The partial oxidation of methane to synthesis gas over CFB using lattice oxygen of the oxygen storage materials instead of gaseous oxygen should be possibly applicable. |
| |
Keywords: | oxygen storage materials air separation partial oxidation synthesis gas circulating fluidized bed rare earths |
本文献已被 维普 万方数据 ScienceDirect 等数据库收录! |
|