冷轧热处理钛-铝箔制备微叠层Ti-Al系金属间化合物板材

通过钛箔、铝箔叠加烧结制备出微叠层Ti-Al系金属间化合物合金板材。对不同烧结条件下获得的板材组织和相组成进行分析。结果表明,当烧结温度到达到Al的熔点以上时,高温自蔓延反应（SHS）在Ti箔和Al箔之间发生,生成α-Ti、Ti3Al、TiAl、TiAl2和TiAl3等相;随着烧结时间的延长,α-Ti、TiAl2和TiAl3逐渐消失,最终获得包含Ti3Al和TiAl的叠层结构板材。由于铝的熔化,柯肯达尔效应和反应前、后摩尔体积的变化在烧结过程中产生大量的孔洞,随后的热压处理将孔洞消除并获得致密的合金板材。

Multilayered Ti-Al intermetallic sheets fabricated by cold rolling and annealing of titanium and aluminum foils

Multilayered Ti-Al based intermetallic sheets were fabricated by sintering alternately layered titanium and aluminum foils. The microstructure and phase formation of the obtained sheets under different sintering conditions were evaluated by various techniques. The results reveal that when the sintering temperature is above the melting point of aluminum, the self-propagating high-temperature synthesis reaction occurs between Ti and Al, and forms various phases of Ti-based solid solutions including α-Ti Ti₃Al, TiAl, TiAl₂ and α-Ti including TiAl₃, etc. When the sintering time increased, Ti-based solid solution, TiAl₂ and TiAl₃ disappeared gradually, and the sheet containing Ti₃Al and TiAl phases in a multilayered structure formed finally. A lot of voids were also observed in the sintered structures, which were caused by the melting Al, Kirkendall effect and the difference of molar volumes between reactants and products. The voids were eliminated and a dense sample was obtained by the following hot press.