| CATALYTICALLY ACTIVE COMPONENTS OF Fe_2O_3-Sb_2O_4 MIXED OXIDE CATALYSTS AND THEIR ROLE IN AMMOXIDATION OF PROPYLENE |
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| 引用本文： | 王誉富,赵新平,吴越. CATALYTICALLY ACTIVE COMPONENTS OF Fe_2O_3-Sb_2O_4 MIXED OXIDE CATALYSTS AND THEIR ROLE IN AMMOXIDATION OF PROPYLENE[J]. 中国化学工程学报, 1986, 1(1): 67-74 |
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| 作者姓名： | 王誉富 赵新平 吴越 |
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| 作者单位： | Chanchun Institute of Applied Chemistry Academia Sinica，Chanchun Institute of Applied Chemistry，Academia Sinica，Chanchum Institute of Applied Chemistry，Academia Sinica |
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| 摘 要： | The catalytically active components of a series of Fe_2O_3-Sb_2O_4 mixed oxide catalysts with differentSb/Fe ratio,calcined at elevated temperature,as well as with or without support,have been investigated byX-ray diffraction analysis,Mossauer spectroscopy and XPS in order to elucidate their catalytic behavior inammoxidation of propylene.Correlations of acrylonitrile yield with Fe~2 and Fe~3 respectively showed that,FeSbO_4 seems to bethe basic active component of catalyst,upon which the formation of new phase containing Fe~3 is responsiblefor a good selective oxidation.
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CATALYTICALLY ACTIVE COMPONENTS OF Fe_2O_3-Sb_2O_4 MIXED OXIDE CATALYSTS AND THEIR ROLE IN AMMOXIDATION OF PROPYLENE |
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| WANG Yufu,ZHAO Xinping,WU Yue. CATALYTICALLY ACTIVE COMPONENTS OF Fe_2O_3-Sb_2O_4 MIXED OXIDE CATALYSTS AND THEIR ROLE IN AMMOXIDATION OF PROPYLENE[J]. Chinese Journal of Chemical Engineering, 1986, 1(1): 67-74 |
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| Authors: | WANG Yufu ZHAO Xinping WU Yue |
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| Affiliation: | Chanchun Institute of Applied Chemistry, Academia Sinica |
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| Abstract: | The catalytically active components of a series of Fe_2O_3-Sb_2O_4 mixed oxide catalysts with differentSb/Fe ratio,calcined at elevated temperature,as well as with or without support,have been investigated byX-ray diffraction analysis,Mossauer spectroscopy and XPS in order to elucidate their catalytic behavior inammoxidation of propylene.Correlations of acrylonitrile yield with Fe~2+ and Fe~3+ respectively showed that,FeSbO_4 seems to bethe basic active component of catalyst,upon which the formation of new phase containing Fe~3+ is responsiblefor a good selective oxidation. |
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