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Characterization and application of a Pt/ZSM-5/SSMF catalyst for hydrocracking of paraffin wax
Affiliation:1. School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;2. Key Laboratory of Coal Gasification and Energy Chemical Engineering of Ministry of Education, Shanghai 200237, China;3. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Dept. of Chemistry, East China Normal University, Shanghai 200062, China
Abstract:The microstructured Pt/ZSM-5/SSMF catalysts, for hydrocracking of paraffin wax, have been developed by impregnation method to place Pt onto thin-sheet ZSM-5/SSMF composites obtained by direct growth of ZSM-5 on the sinter-locked stainless steel microfibers (SSMF). The best catalyst is the one with ZSM-5 having a SiO2/Al2O3 weight ratio of 200, delivering ~ 95% conversion with 77.5% selectivity to liquid products or 64.4% selectivity to naphtha at 280 °C. This new approach is capable of increasing the naphtha selectivity with high activity maintenance in comparison with the literature catalysts.
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