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Solid acid-catalyzed conversion of furfuryl alcohol to alkyl tetrahydrofurfuryl ether |
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| Affiliation: | 1. CAS Key Laboratory of Bio-based Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;1. Catalysis Research Laboratory, Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar 140001, India;2. Nanocatalysis Area Conversion and Catalysis Division, CSIR-Indian Institute of Petroleum, Dehradun 248005, India |
| Abstract: | The acidic zeolite HZSM-5 (Si/Al = 25) achieved 58.9% selectivity of methyl furfuryl ether (MFE) and 44.8% selectivity of ethyl furfuryl ether (EFE) from etherification of furfuryl alcohol with methanol and ethanol. MFE and EFE were quantitatively hydrogenated into methyl tetrahydrofurfuryl ether (MTE) and ethyl tetrahydrofurfuryl ether (ETE) using a Raney Ni catalyst. |
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